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Iron atoms give an air-stable 2D semiconductor magnetism that a gate voltage can tune

NUS-led researchers doped iron into nonmagnetic PtSe2 and used a gate voltage to tune its six-layer Neel temperature from about 25 K to 55 K. Order strengthens as carrier concentration falls, so a gate gives direct control in an air-stable 2D film.

The Scientist · Science desk

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Illustration accompanying Iron atoms give an air-stable 2D semiconductor magnetism that a gate voltage can tune
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Fewer carriers raise the Néel temperature Néel temperature ranges in five- and six-layer Fe-doped PtSe2 devices, and the Curie temperature of bulk Fe-doped PtSe2, in kelvin.

Key figures: in five-layer devices the Néel temperature rose from about 52 K to about 105 K as carrier concentration was reduced; in six-layer devices it was tuned from about 25 K to 55 K; bulk Fe-doped PtSe2 is ferromagnetic with a Curie temperature of about 320 K.

Fewer carriers raise the Néel temperature
FigureValueNoteClaim
Five-layer Néel temperature, reduced carriers, about105 K11
Five-layer start, about52 K11
Six-layer low end, about25 K10
Six-layer high end, about55 K10
Bulk Curie temp, about320 K5

What happened

  • The host, platinum diselenide, is air-stable and metallic in bulk, becomes a semiconductor below about six atomic layers, and is nonmagnetic in pristine form.
  • Bulk iron-doped PtSe2 is ferromagnetic, with a Curie temperature of about 320 K, slightly above room temperature.
  • The thinner devices instead show magnetotransport signatures consistent with antiferromagnetic order, in which neighboring moments favor opposing orientations.
  • In five-layer semiconducting devices the Neel temperature rose from about 52 K to 105 K as carrier concentration was reduced.

Why it matters

  • constraint The gate-tunable order is antiferromagnetic, and the highest value reported, 105 K, is 215 K below the bulk Curie temperature, so no room-temperature switching has been shown.
  • decision Layer count has to be chosen first. Metallic seven-layer devices keep ferromagnetic signatures only at substantially lower temperatures, and the gate response was reported in the thinner devices.
  • capability The source names magnetic order, semiconductor behavior and air stability together as the hard part; this material starts air-stable and keeps its thickness-dependent semiconductor behavior after iron doping.

The gate acts on carrier density. Changing the concentration of charge carriers in the semiconductor changes the magnetic interactions between the iron atoms [8]. In both thicknesses the trend runs the same way: lower carrier concentration, stronger order [9][11]. Six-layer devices show almost no hysteresis at high hole concentration and pronounced hysteresis as the concentration falls [9]. Gating moves the Neel temperature by 30 K in six layers [15] and by 53 K in five [16]. That is roughly a doubling in each case [18].

Atomic-resolution electron microscopy addresses where the iron sits. In the Science Advances paper, a collaboration with scientists in Switzerland, the Czech Republic and Germany [1], the images showed iron substituting directly into the crystal lattice, with no detectable clustering or phase segregation [4]. That matters for reading the magnetic data as a property of the doped crystal itself.

The assignment of antiferromagnetic order in the thin devices rests on transport. The report describes the thin-device signatures as consistent with antiferromagnetic order [7], and the hysteresis as consistent with the electrical activation of that order [9]. Its account of these data does not give the number of devices behind each thickness. In our view the tuning is a credible result that needs a direct magnetic measurement of the thin films to close.

Ahmet Avsar, the NUS assistant professor who led the study [2], put the appeal in terms of the starting material. "What makes this system particularly interesting is that we start from an air-stable, nonmagnetic semiconductor, introduce magnetism, and then control that magnetism electrically," he said. "This combination is exactly what we have been looking for in dilute magnetic semiconductors." [12]

What to watch

  • A direct magnetic measurement of the five- and six-layer films that confirms the antiferromagnetic assignment drawn from transport.
  • Whether the ordering temperature in gated semiconducting devices can be pushed toward the 320 K Curie point of the bulk ferromagnet.
  • Reproduction of the gate-tuned Neel temperatures in other laboratories, with device counts per thickness.

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Evidence62
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  1. [1]

    NUS researchers, in collaboration with scientists from institutions in Switzerland, the Czech Republic and Germany, demonstrated a way to introduce magnetism into an otherwise nonmagnetic 2D semiconductor and control its magnetic properties with an electrical voltage; the findings were published in Science Advances.

    ReportedSupportedSource: phys.org report on the NUS-led studyView cited source
  2. [2]

    The study was led by assistant professor Ahmet Avsar of the Department of Materials Science and Engineering at NUS, with Ph.D. student Qi Zhang as first author.

    ReportedSupportedSource: phys.orgView cited source
  3. [3]

    Platinum diselenide (PtSe2) is an air-stable layered material; bulk PtSe2 is metallic, reducing its thickness below approximately six atomic layers makes it a semiconductor, and in pristine form it is nonmagnetic.

    ReportedSupportedSource: phys.orgView cited source

Sources

1 independent publisher whose own reporting we read for this story.

  1. phys.org

    1 article · October 12, 2026

    From nonmagnetic to magnetic: A 2D semiconductor with electrically tunable magnetism

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