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Liquid metal on a copper cooler turns into solid CuGa2 instead of drying out

Thermal Grizzly boss der8auer's electron-microscope test finds liquid metal on copper turns into solid CuGa2, rated about 100 W/mK against copper's 400. He says nickel plating keeps that layer about 10 times thinner, Tom's Hardware reported.

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Gallium layer on nickel is about 10 times thinner Thickness of the solid gallium layer der8auer reports on copper and on nickel-plated coolers, and the copper compound's rated heat conductivity.

Key figures: on copper the CuGa2 layer reaches about 50 micrometers, up to 100. On nickel-plated coolers the layer is 1 to 5 micrometers, or 5 to 10 on his slide. CuGa2 conducts heat at about 100 W/mK, against roughly 400 for copper.

Gallium layer on nickel is about 10 times thinner
FigureValueNoteClaim
CuGa2 layer on copper, about, at full growth50 micrometersup to 100 micrometers9
Layer on nickel-plated coolers, at least1 micrometersup to 5; 5 to 10 on his slide13
CuGa2 heat conductivity, about100 W/mKcopper: roughly 4006

What happened

  • He saw liquid metal after one hour, then no visible liquid and crystals everywhere at the two-month mark.
  • On the cold plate of Thermal Grizzly's new stainless steel water block, the film could not be wiped off with isopropyl alcohol or acetone after less than five minutes.
  • On aluminum the gallium travels along grain boundaries, and a scrap 2 mm sheet swelled after about five minutes and turned brittle within half an hour.
  • Nickel-plated coolers get NiGa5 instead, a compound of five gallium atoms per nickel atom that likewise stays solid at room temperature.

Why it matters

  • What it limits constraint Heat will not undo the film on a copper cooler, because CuGa2 stays solid up to about 254 degrees C.
  • Who has to decide decision Choosing nickel trades a worse-conducting compound for a thinner film and much less absorbed gallium, and der8auer judges it "most of the time superior".
  • What it costs cost Gallium supply adds cost: Thermal Grizzly pays almost 10 times what it did five years ago, EUR 2,500-3,000 per kilogram against EUR 300.

Nothing evaporates. On copper, the gallium reacts with the metal to form CuGa2, and the leftover indium and tin form other solid areas [6]. The film looks like it is solidifying because it is. Der8auer said the liquid metal "doesn't really dry out" and that it "reacted chemically and it formed a solid compound" [5]. Of the two-year sample he said: "After a total of two years, this honestly did not change further" [3].

He stored the setup in a vacuum or a nitrogen-filled box between sessions to avoid oxidation [4]. A cooler in a running PC gets no such treatment, so the test took oxidation out of the picture.

The conductivity figure is a material rating. CuGa2 is rated at about 100 W/mK against roughly 400 for copper [6], a ratio of 0.25 [20]. Tom's Hardware's account of the video does not include die temperatures before and after, so what a thick film costs a given chip is not measured here. For the quarter-conductivity number to transfer, the film would have to reach full thickness inside the joint, and the chip would have to be limited at that interface.

The growth rate fits the timeline. His example of pure gallium between copper plates at 70 degrees C shows about 4 micrometers over 96 hours [10]. That is 1 micrometer a day [19], the rate he gives for the layer in general, with a ceiling of about 50 to 100 micrometers that depends on temperature and how much gallium is available [9]. At that rate the ceiling arrives in roughly 50 to 100 days [21]. In our view the two-month check, with crystals everywhere, and the unchanged two-year sample fit that [2].

Nickel plating moves the layer to 1 to 5 micrometers, or 5 to 10 on one of his slides [13]. The compound it forms conducts heat worse than the copper-gallium one [14]. The thinner film is therefore a trade against a worse material.

The tester sells both the liquid metal and the remover. Thermal Grizzly sells its own liquid metal as Conductonaut [16]. Its TG Metal Polish & Restore costs $22.11 direct for 30 g of paste, a polishing pen and microfiber cloths, and in a Sept. 30 blog post the company says the paste works as a surfactant, binding the gallium so it cannot stick to the surface again [17]. A PC Games Hardware forum user tried it on an Aqua Computer block that had been cooling a delidded Skylake-X with liquid metal since 2018, and removal took about an hour [18].

Der8auer recommends that liquid metal "stay in the enthusiast bubble" [22].

What to watch

  • Thermal Grizzly's replacement for nickel plating, which der8auer says it hopes to have next year.
  • Measured chip temperatures on copper and nickel coolers after months of aging, which the video as reported does not supply.
  • The new KryoSheet graphene pad for bare dies, which he puts at maybe three or four degrees worse than liquid metal.

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  1. [1]

    YouTuber and Thermal Grizzly boss der8auer tested a two-year-old liquid metal TIM application with an electron microscope and found it does not dry out; the gallium bonds with the copper to form a solid compound.

    Reported Supported Source: Tom's Hardware, reporting der8auer's videoView cited source
  2. [2]

    His test showed the TIM as liquid after one hour, no liquid visible with crystals everywhere at the two-month mark, and then unchanged after two years.

    Reported Supported Source: der8auer, via Tom's HardwareView cited source
  3. [3]

    "After a total of two years, this honestly did not change further," he said.

    Reported Supported Source: der8auerView cited source

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Sources

1 independent publisher whose own reporting we read for this story.

  1. tomshardware.com

    1 article · October 16, 2026

    Experiment shows liquid metal TIM doesn’t dry out; it turns solid

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